Product ID:TPR 9101-84 THERMOPLASTIC RUBBER
MSDS Date:04/01/1989
FSC:6850
NIIN:00N023512
MSDS Number: BLYLT

Emergency Phone: 314-694-1000

Info Phone: 314-694-1000

Cage: 76541

Telephone: 314-694-6661 OR 800-332-3111

Cage: 76541

CARBON BLACK

CAS: 1333-86-4

RTECS: FF5800000

Fraction By Weight: <2.5%

OSHA PEL 3.5 MG/M3

ACGIH TLV: 3.5 MG/M3

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:OCCUPRATIONAL OVEREXP TO MATL HAS NOT
BEEN REPORTED TO CAUSE SIGNIFICANT ADVERSE HUMAN HLTH EFTS.
HOWEVER, TPR RUBBER MAY CNTN TRACES OF ANTIDEGRADANTS &
CROSSLINKERS FOLLOWING MANUFACTURE AND FABRICA TING PROCESSES,
WHICH MAY BE EXUDED TO SURF OF PELLET OR FINISHED PART & CAUSE
SKIN/EYE IRRIT.EXCESSIVE(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:MATL HNDLG OF TPR RUBBR MAY ALSO
CREATE DUST, WHICH MAY ALSO IRRIT EYE/SKIN/RESP TRACT. AT ELEV
TEMPS, TOX VAPS MAY BE RELD WHICH MAY CAUSE IRRIT TO EYE/SKIN/RESP
TRACT. ON THE BASIS OF AVAIL ABLE INFO, EXPOS TO TPR 9101-84 RUBBER
IS NOT EXPECTED TO PRODUCE SIGNIF ADVERSE HUMAN HLTH EFTS WHEN
SAFETY (SUPP DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:SKIN:IMMEDIATELY FLUSH WITH PLENTY OF WATER. REMOVE
CONTAMINATED CLOTHING AND WASH BEFORE REUSE. INHAL:REMOVE TO FRESH
AIR. IF BREATHING IS DIFFICULT, GET MD. REMOVE MATERIAL FROM EYES,
SKIN AND CLOTH ING. INGEST:CALL MD IMMEDIATELY .EYE:FLUSH WITH
POTABLE WATER FOR A MINIMUM OF 15 MINUTES. CALL MD .

Flash Point:>600F,>316C
Extinguishing Media:WATER SPRAY OR ANY CLASS A EXTINGUISHING AGENT.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROT
EQUIP . CO,
Unusual Fire/Explosion Hazard:COMBUSITON PRODUCTS MAY INCLUDE TOXIC
NO*X, CO, HCL & SMOKE.

Spill Release Procedures:WEAR DUST MASK AND GLOVES. MINIMIZE DUST.
VACUUM OR SWEEP UP AND PLACE IN CLEAN COVERED CONTAINER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN COOL, DRY PLACE. USUAL PRECS
IN PELLET HNDLG SHOULD BE OBSERVED TO PVNT CONTAM BY DIRT OR OTHER
MATLS. AVOID BREATHING PROCESSING VAPS/DUST.
Other Precautions:THOROUGHLY PURGE PROCESSING EQUIPMENT WITH POLYOLEFIN
POLYMERS, INCLUDING POLYPROPYLENE, WHEN USING SAME EQUIPMENT TO
PROCESS TPR THERMOPLASTIC RUBBER AND ACETAL RESINS. DO NOT MIX TPR
RUBBER & ACETAL RESINS AT ELEVATED TEMPERATURES.

Respiratory Protection:USE NIOSH/MSHA APPROVED EQUIPMENT WHEN AIRBORNE
EXPOSURE IS EXCESSIVE. CONSULT RESP MFR TO DETERMINE APPROP TYPE OF
EQUIP FOR GIVE APPLIC. OBSERVE RESP USE LIMITS SPECIFIED BY
NIOSH/MSHA/MFR. RESP PRO T PROGRAMS MUST COMPLY W/29 CFR 1910.124
Ventilation:LOC EXHST VENT REC WHERE HIGH TEMP PROCESSING RESULTS IN
GENERATION OF EXCESSIVE SMOKE/OFF-GASES, OR WHERE (SUPP DATA)
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:PROTECTIVE CLOTHING.
Work Hygienic Practices:WASH HANDS/CONTAM SKIN PROMPTLY. LAUNDER CONTAM
CLTHG & CLEAN PROT EQUIP BEFOR REUSE. WASH THOROUGHLY AFTER
HANDLING.
Supplemental Safety and Health
MATLS TO AVOID:& FORMALDEHYDE AS REACTION PROD. EFTS OF OVEREXP:PRECS
REC TO MIN EXPOS ARE FOLLOWED. CARBON BLACK DUST MAY CAUSE
SKIN/RESP TRACT IRRIT. FIBROSIS/OTHER PHYSIOLOGICAL CHANGES IN
LUNGS HA VE BEEN RPTD FOLLOWING PRLNGD/RPTD EXPOS TO CARBON BLACK.
VENT:EXTENSIVE MATL HNDLG RESULTS IN GEN OF DUST/PARTICULATES.

HCC:N1
Spec Gravity:0.84
Appearance and Odor:BLACK PELLETS, SLIGHTLY RUBBERLIKE ODOR

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING CHEM, INCL FLUORINE. ACETAL RESINS AT ELEVATED TEMPS,
PRODUCING DECOMP OF ACETAL RESIN (SUPP DATA)
Stability Condition to Avoid:TEMPS GREATER THAN 400F. IF SUBJECT TO
OPEN FLAMES, GASES WILL BURN & MAY FORM TOX NO*X, CO, HCL & SMOKE.
Hazardous Decomposition Products:SMOKE, CO, NO*X AND POSSIBLY HCL &
HYDROCARBON MAY EVOLVE WHEN PROCESSING TEMPS EXCEED 550F/WHEN
PRODUCT IS IGNITED.

Waste Disposal Methods:NOT HAZARDOUS WASTE AS DEFINED UNDER 40 CFR 261.
BURN IN APPRVD INCINERATOR OR DISP OF IN APPRVD CHEM LANDFILL I/A/W
LOC, STATE & FED LAWS & REGS. CONSULT ATTORNEY OR APPROPRIATE REG
OFFICIALS FOR INF O ON SUCH DISP. DISPOSE OF CNTNRS IN SAME MANNER.

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